I think you have to get the irrigation system adjusted so the well water does not spray on the finishes. I do not believe there is a coating system that will keep the mineralization from forming over time. It will just collect on the coating. You might try some of the anti-graffiti products. There is a chance they will change the look of the materials themselves. Even so, regular cleaning will be necessary. You could also look into products by Prosoco,
http://www.prosoco.com/. I grew up in south Florida where many homes had wells for watering the yards. All had rust stains on their houses from it. When I lived in Chicago, there were numerous metal refinishing companies doing a very good business each year from cleaning the storefronts and other surfaces of buildings from oxidation and winter weather staining.
In your case, fixing the source of the staining seems to be the first thing to correct.
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Roger Retzlaff AIA
Green Bay WI
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